Physics · Chapter 14
Dual Nature of Radiation and Matter
Photoelectric effect, Einstein's equation, de Broglie hypothesis, wave-particle duality — Maharashtra HSC Physics Ch 14
10 formulas · 3 solved examples · 5 practice questions · Board weight: 4 marks · Maharashtra State Board Class 12 · 2025–26 syllabus
Board Exam Tips
- →Einstein's photoelectric equation (hν = φ₀ + K_max) and interpretation of its terms is a 3-mark HSC question every year.
- →Learn Millikan's oil-drop / photoelectric verification and the graph of K_max vs frequency — the slope gives Planck's constant h.
- →de Broglie wavelength derivation from photon momentum p = h/λ and application to matter is a favourite 2-marker.
- →Distinguish clearly between threshold frequency ν₀ and work function φ₀ = hν₀. HSC MCQs commonly test this.
- →State the four experimental laws of photoelectric effect — this alone can give 2 marks in Section B.
Formulas(10)
Energy of a PhotonBoard favourite
| Symbol | Meaning |
|---|---|
| Planck's constant = 6.626×10⁻³⁴ J·s | |
| Frequency of radiation (Hz) | |
| Wavelength (m) |
Momentum of a Photon
Work Function
Einstein's Photoelectric EquationBoard favourite
Stopping PotentialBoard favourite
de Broglie WavelengthBoard favourite
de Broglie Wavelength of Accelerated Electron
Threshold Frequency and Wavelength
Number of Photons per Second
Compton Wavelength (reference)
Solved Examples
A metal has work function 2.5 eV. Find the threshold wavelength.
Convert work function to joules.
Light of wavelength 400 nm falls on a sodium surface of work function 2.3 eV. Find (i) maximum kinetic energy of emitted electrons, (ii) stopping potential.
Photon energy in eV.
An electron and a proton have the same kinetic energy of 100 eV. Find the ratio of their de Broglie wavelengths. (m_p/m_e = 1836)
λ = h/p and p = √(2mK). So for equal K:
Traps & Common Mistakes
- 1
Using photon energy formula E = ½mv² for radiation
✓Photons are massless. Use E = hν = hc/λ, and p = h/λ.
- 2
Assuming photoelectric emission depends on light intensity to eject electrons
✓It depends on frequency being above ν₀. Intensity affects only NUMBER of photoelectrons, not their KE.
- 3
Forgetting to convert eV to joules (or λ from Å to m) in numericals
✓Use consistent SI units, or use the shortcut E(eV) = 1240/λ(nm).
- 4
Mixing up threshold frequency ν₀ with work function φ₀
✓φ₀ = hν₀. ν₀ has units of Hz; φ₀ has units of joules or eV.
- 5
Using de Broglie formula with velocity in km/h or non-SI momentum
✓Use SI units: momentum in kg·m/s. Then λ = h/p in metres.
- 6
Believing photoelectrons take a measurable time to emerge above threshold
✓Emission is instantaneous — this is one of the four laws Einstein explained.
Practice Yourself
- Q1
Find the energy in eV of a 600 nm photon.
- Q2
Work function of caesium is 2.14 eV. What is its threshold wavelength?
- Q3
An electron accelerated through 100 V. Find its de Broglie wavelength.
- Q4
A 60 W source emits light of λ = 620 nm. Find the number of photons emitted per second.
- Q5
State the four experimental laws of photoelectric effect.
Notes
Dual Nature of Radiation and Matter — Maharashtra HSC Overview
Chapter 14 of the Balbharati Class 12 Physics textbook covers the photoelectric effect, Einstein's photon theory, and de Broglie matter waves.
Maharashtra syllabus specifics
- The Balbharati book gives a full historical narrative — Hertz, Hallwachs, Lenard, Millikan — for the discovery of the photoelectric effect. Familiarity with names is expected for a 1-mark MCQ.
- Einstein's equation and its interpretation as a manifestation of Planck's quantum hypothesis is emphasised. HSC expects mention of "photon", "quantum" and "instantaneous emission".
- Davisson–Germer experiment is included in the Maharashtra syllabus as the experimental verification of de Broglie's hypothesis — often asked for 2 marks (description) or as an MCQ.
- The electron microscope and Compton wavelength appear briefly — occasionally asked as a 1-mark objective.
Formula bank shortcut
- E(eV) = 1240 / λ(nm) — memorise this. Cuts calculation time in half.
- λ(Å) for accelerated electron ≈ 12.27/√V — same shortcut.
Board exam pattern
- 4-marker: Einstein's photoelectric equation + graph of K_max vs ν or V₀ vs ν.
- 3-marker: derivation of de Broglie wavelength or numerical on threshold.
- 2-marker: statement of laws of photoelectric effect, or definition of work function.
Related chapters
Related study tips
Deep-dive articles to complement this chapter