Acids, Bases and Salts
Properties of acids and bases, pH scale, salts, water of crystallisation and chlor-alkali process — NCERT Class 10 Chemistry Ch 2
Board Exam Tips
- →pH scale numerical (pH from [H⁺]) — practise both directions.
- →Chlor-alkali process (electrolysis of brine) — a favourite 3-mark diagram question.
- →Preparation and uses of bleaching powder, baking soda, washing soda, plaster of Paris — one of these appears every year.
- →Colour change of indicators — memorise litmus, phenolphthalein and methyl orange.
- →Difference between strong/weak and dilute/concentrated acids — often confused; 2 marks safe.
📐 Formulas(9)
Acid Ionisation in Water★ Board fav
Base Ionisation in Water
Neutralisation★ Board fav
Acid + Metal
Acid + Metal Carbonate
pH Scale★ Board fav
| Symbol | Meaning |
|---|---|
| Molar concentration of H⁺ ions (mol/L) |
Chlor-Alkali Process
Water of Crystallisation
Setting of Plaster of Paris
✏️ Solved Examples
A solution has [H⁺] = 10⁻⁴ M. Find its pH and state whether acidic or basic.
Apply the pH formula
Explain what happens when dilute sulphuric acid is added to sodium hydroxide solution. Write a balanced equation and identify the salt.
It is an acid-base neutralisation. H⁺ from H₂SO₄ combines with OH⁻ from NaOH to give water.
Compound A (used in baking) on heating gives compound B, water and CO₂. B on dissolving in water and recrystallising gives compound C (washing soda). Identify A, B and C with balanced equations.
A is baking soda ⇒ NaHCO₃
⚠️ Traps & Common Mistakes
- 1
Confusing 'strong' with 'concentrated' acid
✓STRONG = fully ionises in water (HCl, H₂SO₄). CONCENTRATED = high amount of acid per litre. A dilute strong acid still ionises 100 %.
- 2
Writing acid + metal → salt + water
✓Wrong. Acid + metal → salt + H₂. Water is a product only with a base or a carbonate.
- 3
Assuming lower pH means less acidic
✓Lower pH ⇒ MORE H⁺ ⇒ MORE acidic. pH 1 is very acidic, pH 6 is mildly acidic.
- 4
Adding water to concentrated acid
✓ALWAYS add acid to water (slowly, with stirring). Reverse can cause splashing and burns due to the exothermic mixing.
- 5
Calling all salts neutral
✓Salt of strong acid + strong base = neutral. Strong acid + weak base (NH₄Cl) = acidic. Weak acid + strong base (Na₂CO₃) = basic.
- 6
Confusing bleaching powder Ca(OCl)Cl with lime CaO or slaked lime Ca(OH)₂
✓Bleaching powder = calcium oxychloride, made from Cl₂ + Ca(OH)₂. Different chemistry, different uses.
🎯 Practice Yourself
- Q1
A solution has pH = 2. Find [H⁺]. Is it acidic or basic?
- Q2
Give the chemical name and formula of (a) baking soda, (b) washing soda, (c) plaster of Paris.
- Q3
State two uses of bleaching powder.
- Q4
Explain the term 'water of crystallisation' with an example.
- Q5
Why does an aqueous solution of NaCl conduct electricity but glucose solution does not?
- Q6
Fresh milk has pH 6. What happens to its pH as it turns to curd? Why?
📝 Notes
Acids, Bases and Salts
Every kitchen, garden and laboratory reaction ultimately traces back to acids and bases — the two 'personalities' of aqueous chemistry.
Arrhenius definitions (Class 10 level)
- Acid: substance that gives H⁺ (or H₃O⁺) ions in water.
- Base: substance that gives OH⁻ ions in water.
- Alkali: a water-soluble base.
- Salt: ionic compound formed from the cation of a base and anion of an acid.
Reactions of acids — must-know four
- With metals: acid + metal → salt + H₂↑
- With carbonates / bicarbonates: acid + carbonate → salt + water + CO₂↑
- With metal oxides / hydroxides (bases): acid + base → salt + water
- In water: dissociation gives H⁺ (H₃O⁺) ions.
pH scale — practical numbers
| pH | Example | |---|---| | 1 | Gastric juice, HCl 0.1 M | | 3 | Vinegar, lemon | | 5.6 | 'Acid rain' threshold | | 7 | Pure water, blood pH ~7.4 | | 9 | Baking soda solution | | 11 | Household ammonia | | 14 | NaOH 1 M |
Living systems are sensitive to pH — human blood must stay between 7.35 and 7.45.
Industrial and household salts
| Salt | Made by | Use | |---|---|---| | Common salt NaCl | Sea water evaporation | Food, chlor-alkali feedstock | | NaOH (caustic soda) | Chlor-alkali process | Soap, paper, textiles | | Bleaching powder Ca(OCl)Cl | Cl₂ + slaked lime | Disinfectant, bleach | | Baking soda NaHCO₃ | Solvay process | Baking, antacid | | Washing soda Na₂CO₃·10H₂O | Recrystallising Na₂CO₃ | Softening water, glass | | Plaster of Paris CaSO₄·½H₂O | Heating gypsum ~373 K | Casts, moulds, boards |
Quick sanity checks
- Universal indicator gives a rainbow: red (acid) → violet (base).
- Neutralisation between strong acid + strong base is always exothermic (~57 kJ per mole H⁺).
- Sudden change of pH by one unit = 10× change in acidity.
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