Periodic Classification of Elements
Dobereiner's triads, Newlands' octaves, Mendeleev's and modern periodic table, trends — Maharashtra SSC Science Part 1 Ch 2
Board Exam Tips
- →Historical timeline (Dobereiner → Newlands → Mendeleev → Modern) — dates and names must match. Frequent 3-mark question.
- →Draw Mendeleev's table with gaps for eka-Si (Ge), eka-Al (Ga); this is a 3-mark diagram.
- →Marathi: गट (group), आवर्त (period), अणुत्रिज्या (atomic radius), विद्युत् ऋणता (electronegativity).
- →Trends along period (L→R): atomic radius decreases, metallic character decreases, electronegativity increases. Down group: opposite.
- →State ONE limitation of Mendeleev vs Modern table — position of H, isotopes, Ar-K order.
📐 Formulas(10)
Dobereiner's Law of Triads
| Symbol | Meaning |
|---|---|
| Atomic masses of first and third elements |
Newlands' Law of Octaves
Mendeleev's Periodic Law★ Board fav
Modern Periodic Law (Moseley, 1913)★ Board fav
Maximum Electrons in Shell (Bohr-Bury)
Valency Rule★ Board fav
Atomic Radius Trend★ Board fav
Electronegativity Trend
Ionisation Energy Trend
Atomic Number and Mass Number
✏️ Solved Examples
Write the electronic configuration of element with atomic number 17 and predict its group and period.
Distribute 17 electrons using 2n^2 rule
Which is more metallic — Na or Mg — and why? State two properties supporting your answer.
Both are in Period 3; Na is Group 1, Mg is Group 2
Element X has electronic configuration 2, 8, 4 and element Y has 2, 8, 7. Predict the formula of the compound between them and the type of bond formed. Also predict their positions in the periodic table.
X: 2,8,4 → Period 3, Group 14 → tetravalent (like C, Si) → Silicon
⚠️ Traps & Common Mistakes
- 1
Saying Mendeleev arranged elements by atomic number
✓Mendeleev used atomic MASS. Atomic NUMBER (Moseley) is the modern criterion.
- 2
Confusing period and group
✓Row = period (horizontal, shell number); column = group (vertical, valence electrons).
- 3
Believing hydrogen belongs only to Group 1
✓H shows properties of BOTH Group 1 (alkali) and Group 17 (halogen) — its exact position is debated.
- 4
Atomic radius increases across a period
✓It DECREASES because nuclear charge increases while shell number stays the same.
- 5
Placing noble gases in Group 0 in the modern table
✓In modern IUPAC table, noble gases are Group 18. 'Group 0' was Mendeleev-era.
- 6
Assuming atomic mass always increases with Z
✓Isotope effects can invert order: Ar (Z=18, mass 40) is heavier than K (Z=19, mass 39.1). Modern table places them by Z.
🎯 Practice Yourself
- Q1
State Mendeleev's periodic law and one merit of his table.
- Q2
Give the group and period of element with Z = 20.
- Q3
Which element has smaller atomic radius: Li or F?
- Q4
Write two limitations of Mendeleev's periodic table.
- Q5
Which family is called alkaline earth metals? Name any two.
- Q6
State Modern Periodic Law.
📝 Notes
Periodic Classification of Elements
Chemistry becomes manageable only after we sort ~118 elements into a periodic pattern. This chapter traces how the pattern was discovered — and how to read it.
SSC angle
Chapter 2 of Science Part 1 typically carries:
- 1-mark: name Mendeleev/Newlands/Moseley, or a group name.
- 3-mark: difference between Mendeleev's and Modern tables, or an atomic-number → group/period problem.
- HOTS: deduce formula & bond type from two electron configurations.
Timeline of classification
| Year | Scientist | Basis | Limitation | |---|---|---|---| | 1817 | Döbereiner | Triads (mass average) | Only a few worked | | 1866 | Newlands | Octaves (every 8th similar) | Failed after Ca | | 1869 | Mendeleev | Atomic mass + valency | H position, isotopes | | 1913 | Moseley | Atomic number Z | Modern law |
Periodic trends — memorise the direction
Across a period (L → R):
- Atomic radius ↓
- Ionisation energy ↑
- Electronegativity ↑
- Metallic character ↓
- Non-metallic character ↑
Down a group (top → bottom):
- Atomic radius ↑
- Ionisation energy ↓
- Electronegativity ↓
- Metallic character ↑
Special families
- Group 1 — Alkali metals (Li, Na, K, Rb, Cs, Fr) — most reactive metals.
- Group 2 — Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra).
- Group 17 — Halogens (F, Cl, Br, I, At) — most reactive non-metals.
- Group 18 — Noble gases (He, Ne, Ar, Kr, Xe, Rn) — inert due to full valence shells.
Board vs CBSE
CBSE covers the same content but often skips deep trend explanations. Maharashtra SSC asks reasoning-based short answers on why radius, IE and EN change the way they do — memorise the reasons, not just the direction.
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