Dual Nature of Radiation and Matter
Photoelectric effect, Einstein's equation, de Broglie hypothesis, wave-particle duality — Maharashtra HSC Physics Ch 14
Board Exam Tips
- →Einstein's photoelectric equation (hν = φ₀ + K_max) and interpretation of its terms is a 3-mark HSC question every year.
- →Learn Millikan's oil-drop / photoelectric verification and the graph of K_max vs frequency — the slope gives Planck's constant h.
- →de Broglie wavelength derivation from photon momentum p = h/λ and application to matter is a favourite 2-marker.
- →Distinguish clearly between threshold frequency ν₀ and work function φ₀ = hν₀. HSC MCQs commonly test this.
- →State the four experimental laws of photoelectric effect — this alone can give 2 marks in Section B.
📐 Formulas(10)
Energy of a Photon★ Board fav
| Symbol | Meaning |
|---|---|
| Planck's constant = 6.626×10⁻³⁴ J·s | |
| Frequency of radiation (Hz) | |
| Wavelength (m) |
Momentum of a Photon
Work Function
Einstein's Photoelectric Equation★ Board fav
Stopping Potential★ Board fav
de Broglie Wavelength★ Board fav
de Broglie Wavelength of Accelerated Electron
Threshold Frequency and Wavelength
Number of Photons per Second
Compton Wavelength (reference)
✏️ Solved Examples
A metal has work function 2.5 eV. Find the threshold wavelength.
Convert work function to joules.
Light of wavelength 400 nm falls on a sodium surface of work function 2.3 eV. Find (i) maximum kinetic energy of emitted electrons, (ii) stopping potential.
Photon energy in eV.
An electron and a proton have the same kinetic energy of 100 eV. Find the ratio of their de Broglie wavelengths. (m_p/m_e = 1836)
λ = h/p and p = √(2mK). So for equal K:
⚠️ Traps & Common Mistakes
- 1
Using photon energy formula E = ½mv² for radiation
✓Photons are massless. Use E = hν = hc/λ, and p = h/λ.
- 2
Assuming photoelectric emission depends on light intensity to eject electrons
✓It depends on frequency being above ν₀. Intensity affects only NUMBER of photoelectrons, not their KE.
- 3
Forgetting to convert eV to joules (or λ from Å to m) in numericals
✓Use consistent SI units, or use the shortcut E(eV) = 1240/λ(nm).
- 4
Mixing up threshold frequency ν₀ with work function φ₀
✓φ₀ = hν₀. ν₀ has units of Hz; φ₀ has units of joules or eV.
- 5
Using de Broglie formula with velocity in km/h or non-SI momentum
✓Use SI units: momentum in kg·m/s. Then λ = h/p in metres.
- 6
Believing photoelectrons take a measurable time to emerge above threshold
✓Emission is instantaneous — this is one of the four laws Einstein explained.
🎯 Practice Yourself
- Q1
Find the energy in eV of a 600 nm photon.
- Q2
Work function of caesium is 2.14 eV. What is its threshold wavelength?
- Q3
An electron accelerated through 100 V. Find its de Broglie wavelength.
- Q4
A 60 W source emits light of λ = 620 nm. Find the number of photons emitted per second.
- Q5
State the four experimental laws of photoelectric effect.
📝 Notes
Dual Nature of Radiation and Matter — Maharashtra HSC Overview
Chapter 14 of the Balbharati Class 12 Physics textbook covers the photoelectric effect, Einstein's photon theory, and de Broglie matter waves.
Maharashtra syllabus specifics
- The Balbharati book gives a full historical narrative — Hertz, Hallwachs, Lenard, Millikan — for the discovery of the photoelectric effect. Familiarity with names is expected for a 1-mark MCQ.
- Einstein's equation and its interpretation as a manifestation of Planck's quantum hypothesis is emphasised. HSC expects mention of "photon", "quantum" and "instantaneous emission".
- Davisson–Germer experiment is included in the Maharashtra syllabus as the experimental verification of de Broglie's hypothesis — often asked for 2 marks (description) or as an MCQ.
- The electron microscope and Compton wavelength appear briefly — occasionally asked as a 1-mark objective.
Formula bank shortcut
- E(eV) = 1240 / λ(nm) — memorise this. Cuts calculation time in half.
- λ(Å) for accelerated electron ≈ 12.27/√V — same shortcut.
Board exam pattern
- 4-marker: Einstein's photoelectric equation + graph of K_max vs ν or V₀ vs ν.
- 3-marker: derivation of de Broglie wavelength or numerical on threshold.
- 2-marker: statement of laws of photoelectric effect, or definition of work function.
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